Dicyclohexylammonium bis(chlorodifluoroacetato-κO)cyclohexyldiphenylstannate(IV)
نویسندگان
چکیده
In the title mixed-organyl stannate, (C(12)H(24)N)[Sn(C(6)H(5))(2)(C(6)H(11))(CClF(2)O(2))(2)], there are two cations and two anions in the asymmetric unit. Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The four Sn-O distances are approximately equal in the two independent anions. Each ammonium cation serves as a hydrogen-bond donor to two stannates, the hydrogen-bonding inter-actions giving rise to linear hydrogen-bonded chains.
منابع مشابه
Dicyclohexylammonium bis(chlorodifluoroacetato-κO)cyclopentyldiphenylstannate(IV)
The five-coordinate Sn atom in the title mixed organyl stannate compound, (C(12)H(24)N)[Sn(C(5)H(9))(C(6)H(5))(2)(C(2)ClF(2)O(2))], is in a trans-C(3)SnO(2) trigonal-bipyramidal coordination environment. The NH(2) groups of the cations act as hydrogen-bond donors to two symmetry-related anions, resulting in the formation of linear chains. One of the phenyl rings is disordered over two sites wit...
متن کاملBis[1,2-bis(diphenylphosphino)ethane-κ2 P:P′]silver(I) bis(chlorodifluoroacetato-κO)(4-chlorophenyl)diphenylstannate(IV)
In the title salt, [Ag(C(26)H(24)P(2))(2)][Sn(C(2)ClF(2)O(2))(2)(C(6)H(5))(2)(C(6)H(4)Cl)], the Ag(I) atom has a tetra-hedral and the Sn(IV) atom a trans-trigonal-bipyramidal coordination geometry. In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two chloro-difluoro-methyl groups are also disordered over two sites for their halogen atoms (occupa...
متن کاملBis[1,3-bis(diphenylphosphino)propane-κ2 P:P′]silver(I) bis(chlorodifluoroacetato-κO)triphenylstannate(IV)
In the title salt, [Ag(C(27)H(26)P(2))(2)][Sn(C(6)H(5))(3)(C(2)ClF(2)O(2))], the Ag(I) atom exists in a tetra-hedral coordination geometry formed by four P atoms [Ag-P = 2.460 (1)-2.501 (1) Å], whereas the Sn(IV) atom exists in a trans-trigonal-bipyramidal coordination geometry formed by two O [Sn-O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn-C = 2.115 (4)-2.128 (4) Å;(Σ C-Sn-C)= 360.0 (...
متن کاملBis[μ-bis(diphenylphosphino)methane-κ2 P:P′]bis[(chlorodifluoroacetato-κO)silver(I)](Ag—Ag)
The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol-ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol-ecule, two bis-(diphenyl-phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro-difluoro-acetate ligand, giving T-shaped geometries and short intra-molecular Ag⋯Ag dista...
متن کاملBis(dicyclohexylammonium) μ-oxalato-κ4 O 1,O 2:O 1′,O 2′-bis[aqua(oxalato-κ2 O 1,O 2)diphenylstannate(IV)]
The structure of the title compound, (C(12)H(24)N)(2)[Sn(2)(C(6)H(5))(4)(C(2)O(4))(3)(H(2)O)(2)], consists of a bischelating oxalate ion, located on an inversion center, which is linked to two SnPh(2) groups. The coordination sphere of the Sn(IV) ion is completed by a monochelating oxalate anion and a water mol-ecule. The Sn(IV) atoms are thus seven-coordinated. The discrete binuclear units are...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008